- Sandwich Shop Restaurants, Demopolis
- Satellite Dish Antennas & Equipment Dealers, Demopolis
- Satellite TV Service, Demopolis
- Sawmill & Planing Mills, Demopolis
- Sawmill Supplies & Equipment Repair, Demopolis
- Sawmill, Paper & Woodworking Supplies, Machinery & Equipment, Demopolis
- Seafood Restaurants, Demopolis
- Secondary Schools, Demopolis
- Security & Surveillance System & Equipment, Demopolis
- Septic Tank Pumping & Cleaning, Demopolis - Septic Systems
- Shoe Stores, Demopolis - Mens, Womens & Kids Shoes
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- Shopping & Shopping Services, Demopolis
- Small Business & Office Equipment Repair Services, Demopolis
- Social Services & Welfare, Demopolis
- Sod & Sodding Service, Demopolis
- Special Interest Schools Or Instruction, Demopolis
- Specialty Stores, Demopolis
- Sporting Goods Stores, Demopolis
- Staffing & Support Services, Demopolis
- State Government, Demopolis
- Surgical Hospitals, Demopolis - Surgical Centers
- Surveyor Services, Demopolis - Surveying Service
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